A new Purdue University-developed process for creating biofuels has shown potential to be cost-effective for production scale, opening the door for moving beyond the laboratory setting.
A Purdue economic analysis shows that the cost of the thermo-chemical H2Bioil method is competitive when crude oil is about $100 per barrel when using certain energy methods to create hydrogen needed for the process. If a federal carbon tax were implemented, the biofuel would become even more economical.
H2Bioil is created when biomass, such as switchgrass or corn stover, is heated rapidly to about 500 degrees Celcius in the presence of pressurized hydrogen. Resulting gases are passed over catalysts, causing reactions that separate oxygen from carbon molecules, making the carbon molecules high in energy content, similar to gasoline molecules.
The conversion process was created in the lab of Rakesh Agrawal, Purdue’s Winthrop E. Stone Distinguished Professor of Chemical Engineering. He said H2Bioil has significant advantages over traditional standalone methods used to create fuels from biomass.
The economic analysis, published in the June issue of Biomass Conversion and Biorefinery, shows that the energy source used to create hydrogen for the process makes all the difference when determining whether the biofuel is cost-effective. Hydrogen processed using natural gas or coal makes the H2Bioil cost-effective when crude oil is just over $100 per barrel. But hydrogen derived from other, more expensive, energy sources – nuclear, wind or solar – drive up the break-even point.
The U.S. Department of Energy and the Air Force Office of Scientific Research funded the research. Agrawal and his collaborators received a U.S. patent for the conversion process.

